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A Journal of Russian Academy of Sciences
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IssuesArchive of Issues2025-6pp.4513-4521

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V.B. Shirokov, I.B. Mikhailova, A.S. Turchin, and V.V. Kalinchuk, "Thermomechanical and Thermophysical Properties of Lithium Niobate," Mech. Solids. 60 (6), 4513-4521 (2025)
Year 2025 Volume 60 Number 6 Pages 4513-4521
DOI 10.1134/S0025654425603350
Title Thermomechanical and Thermophysical Properties of Lithium Niobate
Author(s) V.B. Shirokov (Southern Scientific Center of the RAS, Rostov-on-Donu, 344006 Russia;Southern Federal University, Rostov-on-Donu, 344090 Russia)
I.B. Mikhailova (Southern Scientific Center of the RAS, Rostov-on-Donu, 344006 Russia)
A.S. Turchin (Southern Scientific Center of the RAS, Rostov-on-Donu, 344006 Russia; Southern Federal University, Rostov-on-Donu, 344090 Russia)
V.V. Kalinchuk (Southern Scientific Center of the RAS, Rostov-on-Donu, 344006 Russia, vkalin415@mail.ru)
Abstract A new thermodynamic model of lithium niobate that is based on the use of the sixth-degree Landau potential is proposed. Its feature is the nonlinear dependence of the coefficient at the square of polarization along the polar direction on temperature. In contrast to the previously used fourthdegree potential, this ensures good agreement between the behavior of spontaneous polarization and deformation calculated on its basis and the results of experimental studies. Using the proposed thermodynamic potential, a complete set of material constants determining the thermomechanical properties of lithium niobate, as well as constants of the electro-optical and acousto-optical effects in a wide range of temperature changes, is constructed. Independence of the elastic moduli of lithium niobate from temperature is confirmed, in contrast to piezoelectric, acousto-optical and electro-optical constants, some of which undergo significant changes. The results are of interest when choosing the orientation of the crystal cut in the process of developing micro- and nanoscale acousto- and optoelectronic devices.
Keywords lithium niobate, Landau thermodynamic potential, material constants of linear equations of the piezoelectric effect, electro-optical constants, acousto-optical constants
Received 23 June 2025Revised 09 July 2025Accepted 10 July 2025
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