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IssuesArchive of Issues2022-2pp.292-306

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E. Ya. Denisyuk, "Problems of the Mechanics of Polymer Gels with Unilateral Constraints," Mech. Solids. 57 (2), 292-306 (2022)
Year 2022 Volume 57 Number 2 Pages 292-306
DOI 10.3103/S0025654422020054
Title Problems of the Mechanics of Polymer Gels with Unilateral Constraints
Author(s) E. Ya. Denisyuk (Institute of Continuous Media Mechanics of the Ural Branch of the Russian Academy of Science, Perm, 614013 Russia, denisyuk@icmm.ru)
Abstract Within the framework of the variational approach, boundary value problems are formulated that describe the thermodynamically equilibrium states of statically loaded polymer gels and take into account the conditions of mass transfer of the material with the external environment. A polymer gel is considered as a system that is an elastic (highly elastic) material and a liquid dissolved in it. The liquid (solvent) is assumed to be non-volatile. It is shown that the behavior of the gel depends significantly on the medium in which it is deformed. In particular, when the gel is deformed in the atmosphere, the absorption of liquid by the material from the external environment is excluded; however, it is possible to squeeze out the liquid from the material (in the case of compressive loads). It is shown that such conditions of mass transfer, within the framework of the variational approach, are naturally formulated in the form of one-sided constraints in the form of inequalities. The general theory is illustrated by the example of describing the deformation behavior of polymer gels under conditions of uniaxial tension and compression in a solvent medium and in the atmosphere.
Keywords polymer gels, swelling, finite deformations, thermodynamic equilibrium, chemical potential, osmotic stress tensor
Received 22 February 2021Revised 01 March 2021Accepted 29 April 2021
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