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A Journal of Russian Academy of Sciences
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IssuesArchive of Issues2025-3pp.1666-1676

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V.V. Antipov, S.S. Galkin, A.S. Grashchenko, D.M. Klimov, A.F. Kolesnikov, S.A. Kukushkin, A.V. Osipov, A.V. Redkov, E.S. Tepteeva, and A.V. Chaplygin, "Heat-Resistant Silicon Carbide Coatings on Graphite," Mech. Solids. 60 (3), 1666-1676 (2025)
Year 2025 Volume 60 Number 3 Pages 1666-1676
DOI 10.1134/S0025654424607274
Title Heat-Resistant Silicon Carbide Coatings on Graphite
Author(s) V.V. Antipov (St. Petersburg State Technological Institute (Technical University), St. Petersburg, 190013 Russia)
S.S. Galkin (Ishlinsky Institute for Problems in Mechanics of the Russian Academy of ScienceS, Moscow, 119526 Russia)
A.S. Grashchenko (Institute for Problems in Mechanical Engineering of the Russian Academy of Sciences, St. Petersburg, 199178 Russia)
D.M. Klimov (Ishlinsky Institute for Problems in Mechanics of the Russian Academy of ScienceS, Moscow, 119526 Russia)
A.F. Kolesnikov (Ishlinsky Institute for Problems in Mechanics of the Russian Academy of ScienceS, Moscow, 119526 Russia)
S.A. Kukushkin (Institute for Problems in Mechanical Engineering of the Russian Academy of Sciences, St. Petersburg, 199178 Russia, sergey.a.kukushkin@gmail.com)
A.V. Osipov (Institute for Problems in Mechanical Engineering of the Russian Academy of Sciences, St. Petersburg, 199178 Russia)
A.V. Redkov (Institute for Problems in Mechanical Engineering of the Russian Academy of Sciences, St. Petersburg, 199178 Russia)
E.S. Tepteeva (Ishlinsky Institute for Problems in Mechanics of the Russian Academy of ScienceS, Moscow, 119526 Russia)
A.V. Chaplygin (Ishlinsky Institute for Problems in Mechanics of the Russian Academy of ScienceS, Moscow, 119526 Russia)
Abstract This article proposes and examines a method of forming heat-resistant silicon carbide coatings on graphite products. This coating forms through the simultaneous occurrence of several chemical reactions between silicon melt, carbon monoxide, and the near-surface region of graphite, at temperatures slightly above the melting point of silicon. The resulting coating is several millimeters thick and has high mechanical strength and hardness. Various methods were used to examine the samples, including Raman spectroscopy and SEM. The thermal stability of the coatings was studied by testing them in high-enthalpy subsonic air flows. The results show that the coatings can withstand exposure at temperatures up to 1750°C for 30 minutes. The self-healing mechanisms of the coating under the influence of oxygen at high temperatures were revealed.
Keywords coating, thermochemical resistance, destruction, high-frequency plasmatron, high- enthalpy subsonic air flows, graphite, silicon carbide
Received 31 December 2024Revised 04 January 2025Accepted 04 January 2025
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