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IssuesArchive of Issues2001-5pp.31-46

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A. A. Vakulenko, "On micro and macro kinetics of martensitic transformations," Mech. Solids. 36 (5), 31-46 (2001)
Year 2001 Volume 36 Number 5 Pages 31-46
Title On micro and macro kinetics of martensitic transformations
Author(s) A. A. Vakulenko (St. Petersburg)
Abstract In some publications of the last two decades, martensitic transformations in metals and alloys have been approached by the methods of continuum mechanics. A notable place among these works belongs to the publications by M. A. Grinfeld, who has used the classical variational principles of thermodynamics, formulated by J. Gibbs [1], for the investigation of solid state phase transformations [2]. In these investigations by M. A. Grinfeld, summarized in his monograph [2], the conditions of equilibrium of phases are constructed in a mathematically rigorous way, without any restrictions on the form of the stress state of the phases and the magnitude of their strain (in the classical work by J. Gibbs [1], the famous "phase rule" is obtained under the assumption that the stresses and the strains of all phases are in a "spherical" state). However, the studies described in [2] do not go beyond the conditions of phase equilibrium: the kinetics of martensitic transformations is left untouched. Moreover, for some reason, martensitic transformations are defined in [2] merely as transformations with a coherent interface between the phases, with no additional conditions, although the coherence is neither the only nor the most important feature of martensitic transformations. The basic feature of martensitic transformations is the absence of diffusion, as noticed by G. V. Kurdyumov [3]. All other characteristics of typical martensitic transformations ultimately follow from their being diffusion-free [4]. As shown below, this can be more or less fully taken into account in the framework of continuum mechanics (and thermodynamics). And this provides the possibility for a rigorous derivation of relations that describe the development of martensitic transformations on the macro and the micro levels, in particular, transformations related to the effects of "shape memory" of metallic bodies. To demonstrate this possibility and the ways of its realization is the aim of the present paper.
References
1.  J. W. Gibbs, "On the equilibrium of heterogeneous substances," Trans. Connect. Acad., Vol. 3, pp. 108-203, 1876; Vol. 3,, pp. 345-524, 1878.
2.  M. A. Grinfeld, Methods of Continuum Mechanics in the Theory of Phase Transformations [in Russian], Nauka, Moscow, 1990.
3.  G. V. Kurdyumov and L. G. Khandros, "On thermoelastic equilibrium in martensitic transformations," Doklady AN SSSR, Vol. 66, No. 2, pp. 211-214, 1949.
4.  G. Christian, Theory of Transformations in Metals and Alloys. Part 1. Thermodynamics and the General Kinetic Theory [Russian translation], Mir, Moscow, 1978.
5.  K. M. Weiman, "Martensitic transformations. Investigations by electron microscope and diffraction methods," in Diffraction and microscoping methods in materials science [Russian translation], pp. 128-181, Mir, Moscow, 1984.
6.  Shape Memory Effects in Alloys [in Russian], Metallurgia, Moscow, 1979.
7.  A. I. Lur'e, Nonlinear Theory of Elasticity [in Russian], Nauka, Moscow, 1980.
8.  A. I. Lur'e, Theory of Elasticity, Nauka, Moscow, 1970.
9.  A. Goland, "Modern studies on point defects in metals," in Point Defects in Solids [Russian translation], Mir, Moscow, 1979.
10.  P. Honeycomb, Plastic Deformation of Metals [Russian translation], Mir, Moscow, 1972.
11.  J. P. Hirth and J. Lothe, Theory of Dislocations [Russian translation], Atomizdat, Moscow, 1972.
12.  L. A. Girifalco, Statistical Physics of Materials [Russian translation], Mir, Moscow, 1975.
13.  L. M. Zubov and A. N. Rudev, "A canonical representation for the deviator of a symmetric tensor," Doklady AN, Vol. 358, No. 1, pp. 44-47, 1998.
14.  I. R. Prigogine, "Étude thermodynamique des processes irreversible", Dunod, Paris, 1947.
15.  A. A. Vakulenko, "On the theory of irreversible processes", Vestnik LGU, Vol. 7, No. 2, pp. 84-91, 1969.
16.  A. A. Vakulenko, "Superposition in the rheology of continuous media," Izv. AN SSSR. MTT [Mechanics of Solids], No. 1, pp. 69-76, 1970.
17.  A. A. Vakulenko, "Relations between micro and macro properties of elastic-plastic media," in Advances in Science and Technology. Ser. Mechanics of Solids. Volume 22 [in Russian], pp. 3-54, VINITI, Moscow, 1991.
Received 01 February 2000
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